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Multi-walled carbon nanotubes were used to deposit Ru metal by electrostatic adsorption and incipient wetness impregnation methods, respectively. The electrostatic adsorption method led to small (1.8–2.5nm) and highly dispersed (0.51–0.72 dispersion) Ru metal nanoparticles. The initial hydrogen generation turnover rates over Ru catalysts with different metal particle sizes showed that ammonia borane...
The initial hydrogen generation turnover rates during the hydrolysis of sodium borohydride over nickel catalysts (crystalline nickel (Ni), crystalline nickel boride (Ni3B), and amorphous nickel–boron (Ni–B) nanoparticles) were measured to investigate the reaction kinetics and mechanisms by varying the reactant concentrations and reaction temperatures. Nickel catalysts with and without boron follow...
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