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We report here a novel protein sequestration method using polymeric colloidal particles prepared by emulsion polymerization with reactive block copolymers. Specifically, poly(4-vinyl-N-ethylpyridine bromide)-block-polymethylacrylate block copolymers were synthesized from reversible addition–fragmentation chain transfer polymerization and used as emulsifiers for emulsion polymerization of poly(4-vinyl-N-ethylpyridine...
A facile “one-pot” emulsion polymerization is reported to prepare surface-functionalized sub-micron spheres using novel amphiphilic comonomer as the reactive emulsifier. Specifically, amphiphilic 3-[2-(acryloyloxy)ethoxy]-3-oxopropyl(phenyl) phosphinic sodium (AEOPS) was used not only as a comonomer, but also as a good emulsifier for the polymerization due to the relatively long chain of amphiphilic...
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