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Cubic sodium Prussian White, Na2-xFe2(CN)6·yH2O, and potassium Prussian White, K2-xFe2(CN)6·yH2O, are prepared following a mild synthetic methodology. While cubic symmetry is confirmed by XRD and TEM, IR and XPS show characteristic features different from Prussian Blue compositions. When investigated as cathode materials in sodium ion batteries, both compounds exhibit reversible capacities above 140 mAh g...
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