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The energetics at organic‐metal interfaces are, to large extend, determined by the structure of the molecular adsorbate on the substrate surface. As shown by low‐energy electron diffraction (LEED) the zigzag shape of picene leads to a peculiar monolayer structure on Ag(111), Ag(110), and Cu(111) with one molecule in the unit cell lying essentially flat and the other one adopting an edge‐on orientation...
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