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A synthesis of new chiral dihalo palladium(II)-(5, 7) and nickel(II) (6, 8) complexes bearing the ligands N,N'-bis{(-)-(cis)-myrtanyl}butylene-2,3-diimine (BMDI, 3) and the conformationally constrained bisoxazoline ligand ((1R,2S)-inda-box, 4) is described. Reaction of [(TMEDA)Pd(CH 3 )Cl] (TMEDA: N,N,N',N'-tetramethylethylenediamine) with 4 followed by chloride abstraction with NaB(Ar ...
Preparation of four dimeric nickel(II) complexes and three monomeric palladium(II) complexes bearing didentate pyridinylimine ligands is described. The solid-state structures of these compounds have been determined by single-crystal X-ray diffraction. After activation with methylaluminoxane (MAO) the nickel compounds were used as catalysts in ethylene polymerization producing nearly linear or primarily...
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