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LiMn 2 O 4 spinels were studied with the aim of assessing the role of different types and amounts of defects in blocking the phase transition from spinel to double hexagonal that is associated with anomalous 4.5 and 3.3/3.95V redox steps. The influence of the type of MnO 2 precursor (β or γ, both with diverse amounts of stacking faults), the effect of introducing defects in...
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