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The local environment of arsenic atoms in vitreous samples of the system Sb2S3–As2S3–Tl2S has been studied by EXAFS at the AsK-edge. The crystalline compound Tl5.6As15S25.3 situated within the zone of glass formation of the Sb2S3–As2S3–Tl2S phase diagram was used as reference compound in order to derive appropriate phase and amplitude functions. The structure parameters determined were the number...
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