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The efficient narrow band emission of Eu2+ in Cs2MP2O7 (M = Ca2+, Sr2+) is characterized by a large Stokes shift and a high quenching temperature which makes the material promising for application in warm white LEDs. The unusual Eu2+ luminescence properties were reported recently but an explanation for the peculiar behavior is lacking. In this paper we aim at providing new insights in the luminescence...
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