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Sn sitzt locker: Der bevorzugte Verlauf für die dehydrierende Kupplung von Stannanen durch den d0‐Komplex [Cp2(Cl)HfH] wurde ermittelt (siehe Schema): Auf eine σ‐Bindungsmetathese unter Bildung von [Cp2(Cl)Hf(SnH3)] folgt ein Stannyleneinschub in eine Cp2(Cl)Hf‐SnH3‐Bindung. [Cp2(Cl)Hf(SnH3)] isomerisiert leicht zu [Cp2(Cl)Hf(μ‐H)SnH2], einer Spezies mit reaktiver Stannyleneinheit, sodass der Stannylentransfer...
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