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The reaction of amine phosphates with metal ions, under mild conditions, has been utilized for the synthesis of open-framework phosphates. Two new amine phosphates, DABCO-phosphate and imidazole-phosphate, synthesized for the first time, were employed for this purpose. Thus, DABCO-phosphate reacts with Co(II) and Zn(II) ions giving rise to open-framework structures, of which [C 6 N 2 ...
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