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Octahedral Mn-MIL-100 metal-organic frameworks (MOFs) are first synthesized, which are then used as templates to fabricate the porous Mn2O3 octahedra through a post-calcination strategy. The morphologies and crystalline structures of as-prepared Mn2O3 octahedra are performed by using field-emission scanning electron microscopy (FESEM), X-ray diffraction (XRD) and transmission electron microscopy (TEM)...
Hollow NiO microspheres with porous shell are synthesized through the ion exchange of a facile zinc citrate template with the subsequent chemical etching. As an anode material for LIBs, the porous hollow NiO electrode shows much higher reversible capacity and better cycling stability in comparison with the ZnO–NiO composite. After 400cycles under a high current rate of 1C, the discharge capacity of...
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