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Electrodeposition of BaCO3 from aminecarboxylate stabilized-Ba(HCO3)2 baths, results in oriented crystallization when the bath conditions promote the decomposition of the Ba complex. Crystal growth is predominant along the c-crystallographic axis. The crystallites orient themselves with their c-axis normal to the substrate. The crystallites exhibit three-fold twinning (trilling) consequent to the...
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