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Eine kryogene Technik …︁…︁ zur Beladung von porösen Metall‐organischen Gerüststrukturen mit Gasmolekülen beschreiben S. A. Moggach et al. in der Zuschrift auf S. 13530 ff. Bei diesem üblicherweise von Physikern und Planetenwissenschaftlern genutzten Verfahren wird eine Diamantstempelzelle mit verflüssigten Gasen beladen. Im vorliegenden Fall wurden CO2 und CH4 in ein Scandium‐basiertes MOF gefüllt...
An alternative approach to loading metal organic frameworks with gas molecules at high (kbar) pressures is reported. The technique, which uses liquefied gases as pressure transmitting media within a diamond anvil cell along with a single‐crystal of a porous metal–organic framework, is demonstrated to have considerable advantages over other gas‐loading methods when investigating host–guest interactions...
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