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Flory–Huggins interaction parameter (χ pd ) was introduced to qualitatively evaluate the drug–polymer compatibility between hydrophilic 5-fluorouracil (5-FU) and hydrophobic core block, which was formed by poly[γ-(carbamic acid benzyl ester)-ɛ-caprolactone] (PCABCL) and poly(ɛ-caprolactone) (PCL). The calculation results indicated that PCABCL had better affinity with 5-FU than PCL. Thus, a...
Binary blend compatibility of chitosan (CS) and poly(ϵ‐caprolactone) (PCL) was simulated at different blending ratios in molecular and mesoscopic level. In molecular simulation, Flory–Huggins interaction parameters and mixing enthalpies were calculated to estimate the blend compatibility. Results showed that compatibility of CS/PCL blends reduced with increase of PCL content. Plots of free energy...
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