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Ring-opening polymerization of 1,5-dioxepan-2-one (DXO) initiated with aluminium isopropoxide in tetrahydrofuran (THF) solution and in bulk has been investigated. An improved monomer purification procedure is presented which makes it possible to synthesize high molecular weight poly(DXO) with a narrow molecular weight distribution. The kinetic dependence on parameters such as polymerization temperature,...
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