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Resonance Raman spectra are reported for the carbon monoxide (CO) adduct of catalase formed from the reaction of peracetic acid or hydrogen peroxide with the azide adduct or catalase in the presence of CO. The expected three normal vibrations of the Fe CO fragment are detected at 1,908, 593 and 543 cm -1 for the ν(C O), δ(Fe C O) and ν(Fe CO), respectively. The expected coordination...
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