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Raman‐Spektren oxygenierter Zwischenstufen von humanem CYP17, das in Nanoscheiben eingebettet wurde, in Gegenwart natürlicher Substrate (Pregnenolon und Progesteron) bestätigen direkt, dass die Substratstruktur die Wasserstoffbrücken zu dem entscheidenden Fe‐O‐O‐Fragment modifiziert und dieses in Richtung eines von zwei alternativen Reaktionspfaden lenkt. Eine derartige Substratkontrolle hat große...
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