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Superoxide reductase (SOR), a non‐heme mononuclear iron protein that is involved in superoxide detoxification in microorganisms, can be used as an unprecedented model to study the mechanisms of O2 activation and of the formation of high‐valent iron–oxo species in metalloenzymes. By using resonance Raman spectroscopy, it was shown that the mutation of two residues in the second coordination sphere...
Spalten und übertragen: Ein Sensibilisator‐Dieisen(III)‐Komplex wurde in Gegenwart eines Elektronendonors erst belichtet und dann O2 ausgesetzt. Der Komplex wandelt sich dabei in eine aktive Dieisen(III)‐Peroxo‐Spezies um, die ein Sauerstoffatom auf ein Substrat übertragen kann (siehe Schema).
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