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A new type of 90-240 G wide EPR signal from the modified S 3 state of Ca 2+ -depleted photosystem II (PSII) is concluded to arise from a partially oxidized water radical with spin S = 1 interacting with the S =1 S 2 -state manganese tetramer ( Mn 4 ). This is based exclusively on the fact that the average g value of the radical is 2.010-2.012, a value close...
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