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Metalloporphyrins (MP) are often employed in biomimetic catalysis due to their structural and functional similarity to the heme prosthetic group of oxygenating enzymes. In these enzymes, the iron porphyrin is primarily protein-bound at the active site by cysteine (cytochrome P450, CYP), histidine (peroxidase), and tyrosine (catalase), acting as axial ligands. The diverse functionality and variable...
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