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At pH 3.0 in the absence of a reducing substrate and the presence of only 20 equivalents of H 2 O 2 , lignin peroxidase (LiP) is readily converted to LiP compound III (LiPIII) (Fe(III)O -2 - complex). LiPIII which is produced via the reaction of LiP compound II (LiPII) with H 2 O 2 is not part of the peroxidase catalytic cycle, and is readily and irreversibly...
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