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The total solid phase synthesis of an analogue of the B ring of nisin was achieved, in a biomimetic fashion, via the solid phase diastereoselective cyclisation of a dehydrothiol-containing peptide.
Lanthionine is an attractive monomer for the design and synthesis of novel conformationally constrained peptidomimetics, since unlike cystine, the monosulfur bridge of lanthionine is chemically far more robust and also displays a greater degree of conformational rigidity. The synthesis of lanthionine residues for use in peptide synthesis is non-trivial due to the protectional requirements necessary...
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