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Examples of boron-insertion reactions are presented in which either a functionalized alkene or alcohol is inserted into the open face of a dicarbollide ion. Boron-insertion products of both ortho- and meta-carborane are synthesized, such as closo-3-(3-bromopropyl)-1,2-dicarba-dodecaborane, 6a, and closo-2-(3-bromopropyl)-1,7-dicarbadodecaborane, 6b. While the ortho-3- and meta-2-alkylhydroxy-carborane...
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