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The optimization of the electronic properties of molecular materials based on optically or electrically active organic building blocks requires a fine‐tuning of their self‐assembly properties at surfaces. Such a fine‐tuning can be obtained on a scale up to 10 nm by mastering principles of supramolecular chemistry, i.e., by using suitably designed molecules interacting via pre‐programmed noncovalent...
The image shows a 3D representation of a new class of macromolecules for organic electronics formed by rigid polymeric backbones (blue) side‐functionalized with thousands of polyaromatic, optically active molecules (red). In the background, the real polymer fibers as presented by V. Palermo, K. Müllen, D. Beljonne, R. H. Friend, A. E. Rowan, P. Samorì, et al. on p. E81 are visualized by AFM. The authors...
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