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We demonstrated that the ring-opening metathesis polymerization (ROMP) of 3-substituted cyclooctenes bearing polar substituents allows the synthesis of highly regio- and stereo-regular polymers. A series of polyalkenamers with 90–99 % head-to-tail/trans configuration were synthetized in good yields (33–87 % yield). Upon saturation of the backbone using diimide, these polymers represent a class of...
Since its recent successful isolation, graphene has attracted an enormous amount of scientific interest due to its exceptional physical properties. Graphene incorporation can improve electrical and mechanical properties of polymers including polyethylene (PE). However, the hydrophobic nature and low polarity of PE have made effective dispersion of nano-fillers difficult without compatibilization....
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