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Porous polymeric layer‐by‐layer self‐assembled films with enhanced electrochromism are demonstrated by P. S. Lee and co‐workers on page 401 using polyaniline and polymeric complexes as building blocks. These films show fast growing behavior as well as enhanced optical modulation and fast switching speed. This image portrays the facilitated diffusion of ions into the porous films during the redox reaction...
In this work, a facile method to deposit fast growing electrochromic multilayer films with enhanced electrochemical properties using layer‐by‐layer (LbL) self‐assembly of complex polyelectrolyte is demonstrated. Two linear polymers, poly(acrylic acid) (PAA) and polyethylenimine (PEI), are used to formulate stable complexes under specific pH to prepare polyaniline (PANI)/PAA‐PEI multilayer films via...
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