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Catecholatoiron complexes were isolated in the crystalline or non-crystalline form from the reaction solution of catechols with FeCl 3 in the presence of pyridine in THF; they form a functional model system for catechol dioxygenases. Two types of complex were obtained, depending on substituents on catechol and pyridine: [FeCl (catechol)(pyridine)](pyridine) and [FeCl 2 (catechol)]...
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