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Photoreduction of gaseous carbon dioxide to carbon monoxide with hydrogen over Rh-loading TiO 2 was investigated. As the reaction proceeded even in the dark but was enhanced under irradiation, the reaction should be considered as “photo-enhanced reaction”. When Rh in Rh/TiO 2 was strongly reduced to be in a fully metallic state, the activity was lowered and the main product changed...
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