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In this paper, the two-step hydrate formation mechanism proposed by the authors (Chen and Guo, 1998) has been extended to structure-H hydrates (sH). It was assumed that the basic sH hydrate can be formed by large molecules only, termed as sH hydrate formers. A hydrate model based on this formation mechanism has been developed, in which the evaluation of both the thermodynamic parameters of an unstable...
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