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Room for accommodation: A novel porphyrin‐related macrocycle was constructed by replacement of the dipyrromethene unit with a 1,10‐phenanthroline moiety. This macrocycle is capable of complexation and fluorescent detection of Mg2+ with high selectivity over other physiologically relevant metal ions such as Na+, K+, and Ca2+. It functions well as a fluorescent sensor for Mg2+ even in HEPES buffered...
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