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Structural variants of high‐nuclearity clusters are extremely important for their modular assembly study and functional expansion, yet the synthesis of such giant structural variants remains a great challenge. Herein, we prepared a lantern‐type giant polymolybdate cluster (L‐Mo132) containing equal metal nuclearity with the famous Keplerate type Mo132 (K‐Mo132). The skeleton of L‐Mo132 features a...
Structural variants of high‐nuclearity clusters are extremely important for their modular assembly study and functional expansion, yet the synthesis of such giant structural variants remains a great challenge. Herein, we prepared a lantern‐type giant polymolybdate cluster (L‐Mo132) containing equal metal nuclearity with the famous Keplerate type Mo132 (K‐Mo132). The skeleton of L‐Mo132 features a...