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Gas-phase ion/ion reactions between multiply deprotonated DNA and RNA anions and rubrene radical cations have been investigated in this research. Ion/ion reactions of DNA 6-mer (dT 6 , dC 6 , dA 6 and dG 6 ) anions with rubrene radical cations led to negative electron transfer dissociation (nETD), complex formation, and negative electron transfer without dissociation...
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