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In this report, the stepwise synthesis of a novel rigid and functionalised macrocycle 2 based on triazine and phenylenediamine linkers, is presented. Poor recognition of the macrocycle 2 for its substrates is observed, which shows experimentally that for the meltriazine based-calix[6]arene system, the binding ability of the melamine moiety gets more benefit from the ring flexibility derived from a...
The synthesis of a non-peptidic triazine-based macrocyclic scaffold is presented. The strategy employed allows for the facile functionalisation of the macrocyclic molecules and combinatorial construction of putative receptor molecules.
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