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Die selektive N‐Acylierung von Glucosamin mit ungeschützten Carbonsäuren ermöglicht die Biosynthese nichtnatürlicher Glycoside. In ihrer Zuschrift auf S. 5346 veranschaulichen L. Liu, S. L. Flitsch, J. Voglmeir et al. die breite N‐Acylierungsaktivität des Enzyms Chitobiose‐Deacetylase aus Cyclobacterium marinum mit nichtaktivierten Carbonsäuren. Unter Verwendung dieser selektiven N‐Acylierung gelingt...
Chitin is one of the most abundant and cheaply available biopolymers in Nature. Chitin has become a valuable starting material for many biotechnological products through manipulation of its N‐acetyl functionality, which can be cleaved under mild conditions using the enzyme family of de‐N‐acetylases. However, the chemoselective enzymatic re‐acylation of glucosamine derivatives, which can introduce...
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