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Inhärent chirale ionische Flüssigkeiten …… bestehend aus 1,1′‐Dialkyl‐3,3′‐bicollidinium‐Salzen können ausgezeichnet zwischen den Enantiomeren chiraler Sonden auf achiralen Elektroden differenzieren, selbst wenn sie einer achiralen ionischen Flüssigkeit nur in niedriger Konzentration zugesetzt werden. Einzelheiten erläutern P. R. Mussini, F. Sannicolò et al. in ihrer Zuschrift auf S. 2111. Im Bild...
To achieve enantioselective electroanalysis either chiral electrodes or chiral media are needed. High enantiodiscrimination properties can be granted by the “inherent chirality” strategy of developing molecular materials in which the stereogenic element responsible for chirality coincides with the molecular portion responsible for their specific properties, an approach recently yielding outstanding...
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