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Reduced wear rates of filled polymeric tribomaterials consistently accompany improvements in the appearance of the transfer film, a protective layer of debris that adheres to the counterface. As a result, wear reductions are often attributed to the favorable effects of the filler on transfer film quality. However, the cause-effect relationship between fillers, transfer film quality, and polymer wear...
The transfer film, a protective barrier that forms when a solid lubricant slides against a hard and high-surface-energy counterface, plays an important role in friction and wear reduction. The transfer films of many solid lubricants are removed and replenished during sliding. However, one particularly low wear rate solid lubricant has been shown to produce persistent transfer films that thicken and...
Solid lubricant materials have become necessary in applications for which traditional lubrication approaches become impractical. These materials are often mated against a harder metallic counter surface (counterface) of higher surface energy. During sliding, wear fragments from the solid lubricant transfer to the counterface to form a protective barrier known as the transfer film. Historically, the...
Polytetrafluoroethylene (PTFE) is an important solid lubricant with an unusually high wear rate. For a half-century, fillers have been used to reduce PTFE wear by >100× with >10% loading through hypothesized mechanisms involving mechanical load support, crack arresting, and transfer film adhesion. More recently it was discovered that specific nanoparticles provide a unique nanoscale reinforcement...
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