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AbstractStereoselectivity in the oxidation of ferrocenyl sulphides with several species of microorganisms such as Corynebacterium equi was reversed between (methylthiomethyl)ferrocene and (t-butylthiomethyl)ferrocene, indicating that the size of the side chain could control the stereochemical course of the biooxidation. The size seems to be effective within some limit, because the more bulky compound,...
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