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Bis(3,5-di-tert-butylsalicylaldiminato)Cu(II) complexes were prepared in high yields from a sterically hindered 3,5-di-tert-butylsalicylaldehyde and a variety of amines using three synthetic approaches. They were all thoroughly characterized by various spectroscopic methods (UV–Vis, IR, EPR and EI-MS). Crystal structures of seven complexes determined by X-ray crystallography show the Cu ion in a N...
A series of bis(3,5-di-tert-butylsalicylaldimine)copper(II) complexes were synthesized and employed in the catalytic oxidation of alcohols using molecular oxygen as a terminal oxidant. These complexes, when combined with TEMPO form a highly efficient catalytic system for the aerobic oxidation of primary benzylic and allylic alcohols under mild reaction conditions. For example at 60°C and 1bar of O...
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