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A new process for the electrolytic production of magnesium from its oxide is described, based on the reaction MgO + NdCl3→MgCl2 + NdOCl. This is followed by electrolysis of the resulting MgCl2/NdCl3/NdOCl melt using a carbon anode, the proposed electrolysis reaction being 2MgCl2+C+ 2NdOCl→2Mg + CO2 + 2NdCl3. XRD studies confirm the formation of NdOCl when MgO is fused with NdCl3. Electrolysis of the...
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