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Reaction of metal salts CoCl2·6H2O,NiCl2·6H2O and Na2[PdCl4] with thymine bisdithiocarbamate and uracil bisthiocarbamate in molar ratio 2:1 (metal/ligand) affords the presumably tetrahedral complexes [M2(dtc)(H2O)4Cl2] M; Co, Ni and square planer complexes [Pd(dtc)(H2O)4Cl2] dtc=tdtc, utdc. Dithiocarbamates (dtcs) behave as monodentate ligands. Reaction of [M2 dtc (H2O)4Cl2] M; Co (II), Ni (II), and...
This research includes synthesis and characterization of some homogeneous binuclear complexes of Co(II), Ni(II), and Pd(II) with mixed ligands of thiuram, uracil thiuram disulfur or thymine thiuram disulfur, and cyclic amines. The formed complexes have the general formula of [M2(L)1(amin)2] where L = (thymine thiuram disulfur), (uracil thiuram disulfur) = (T‐TDS), (U‐TDS), amin = (1,10‐Phen.) (2,2′‐BiPy...