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In this article we use fluorescence resonance energy transfer (FRET) to investigate how a classic coalescing aid, such as 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate (Texanol™) (TX), acts on the earliest stages of polymer diffusion as the latex film is still drying. In our approach, we temporarily arrest the drying process of a partially wet latex film by sealing it in an airtight chamber previously...
This paper describes experiments that investigate the use of low glass transition temperature (Tg) latex particles consisting of oligomer to promote polymer diffusion in films formed from high molar mass polymer latex. The chemical composition of both polymers was similar. Fluorescence resonance energy transfer (FRET) was used to follow the rate of polymer diffusion for samples in which the high...
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