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The excitation and emission spectra of CsCdCl 3 crystal grown by the Bridgman growth technique, are observed. Its dominant excitation spectra correspond to the transitions between the electronic energy levels of the face-shared [CdCl 6 ] 4− octahedron complexes with C 3v symmetry. With the help of the molecular orbital diagram of the [CdCl 6 ] 4− molecule...
The RbCdBr3 crystal that consists of edge shared [CdBr6]4− octahedrons was grown by using the Bridgman growth technique and its electronic energy levels are investigated by measuring the excitation and the emission spectra. An energy level diagram for electronic energy levels of RbCdBr3‐crystal is constructed by using the observed excitation spectra and symmetry considerations.
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