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Lanthanide (Ln) tetraisobutylaluminates constitute key components in commercial 1,3‐diene polymerization catalysts, and likewise are the homogeneous rare‐earth‐metal catalysts of prime industrial importance. Discrete divalent rare‐earth‐metal complexes [Ln(AliBu4)2] (Ln=Sm, Eu, Yb) reported here display the first structurally characterized homoleptic metal tetraisobutylaluminates. Treatment of [Ln(Al...
Lanthanoid (Ln)‐Tetraisobutylaluminate sind Schlüsselkomponenten in kommerziell genutzten Katalysatoren für die 1,3‐Dienpolymerisation und sind gleichsam Seltenerdmetall‐Katalysatoren von wesentlicher industrieller Relevanz. Die hier beschriebenen, diskreten zweiwertigen Seltenerdmetall‐Komplexe [Ln(AliBu4)2] (Ln=Sm, Eu, Yb) sind die ersten strukturell charakterisierten, homoleptischen Tetraisobutylaluminat‐Komplexe...
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