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Isopropylation of biphenyl (BP) over [Al]-SSZ-31, a large-pore, one-dimensional zeolite has been studied. Effects of temperature, pressure and SiO2/Al2O3 ratio were examined. SSZ-31 was found to be an active catalyst in the isopropylation of biphenyl with propylene. The selectivity for 4-isopropylbiphenyl (4-IPBP) and 4,4′-diisopropylbiphenyl (4,4′-DIPB) was high among isopropylbiphenyl (IPBP) and...
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