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Ionic and free radical addition of halogen systems were carried out with perfluoroheptene-1 (1), octafluorocyclopentene (2), 1H,1H,2H-perfluorooctene-1 (3) and perfluoro-4-methyl-2-pentene (4). The terminal alkene 1 was treated with chlorine in tert-butyl alcohol as solvent with mercury catalyst under reaction conditions that assure an ionic pathway. Bromine did not react with 1 under similar conditions...
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