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News from FeC: The title ternary rare‐earth compounds contain planar (magnetic) Fe6 clusters interlinked by Fe(C2)3 units to form polymeric carboferrate complexes (see structure; red Fe, black C). The Fe6 clusters can be regarded as fragments of γ‐Fe and binary iron carbides. The chemical bonding situation in the ternary compounds is characterized by covalent FeFe, polar dative ligand (C2)→metal...
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