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Hexacyanoferrate on intercalation within the interlayer region of the layered double hydroxide (LDH) of Mg with Al retains its electroactivity. Within the confined region of the interlayer, the redox potential of the intercalated ion, as estimated from cyclic voltammetric studies, is shifted by almost 126mV higher than that of the free ion in solution. We attribute this to the activity of hydroxyl...
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