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Cathodic reduction of an aqueous solution containing dissolved calcium and phosphate ions results in the deposition of micrometer thick CaHPO4·2H2O (dicalcium phosphate dihydrate) coatings on stainless steel substrates. The coating obtained at a low deposition current (8 mA cm − 2) comprises lath-like crystallites oriented along 020. The 020 crystal planes are non-polar and have a low surface energy...
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