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The binary antimonide Ti 2 Sb crystallizes in a unique structure type, which may be considered as a distorted variant of the La 2 Sb structure type. The new ternary variants, Ti 2−δ M δ Sb (M=Zr, Hf) with δ<0.85, were prepared by arc melting the elements in stoichiometric ratios. The ternaries crystallize in the body centered tetragonal space group I4/mmm, with lattice...
The two new ternary scandium tellurides SrSc 2 Te 4 and BaSc 2 Te 4 were prepared by heating the elements at temperatures between 800°C and 900°C under vacuum. Both compounds crystallize in the CaFe 2 O 4 type, space group Pnma, Z=4, with lattice dimensions of a=13.1795(17)Å, b=4.2323(7)Å, c=15.367(2)Å, V=857.2(2)Å 3 for SrSc 2 Te ...
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