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Binary intercluster compounds (IC) can be reduced to basic structure types of ionic solids. We examined the validity of this concept for ternary compounds, on the example of a quasi-ternary intercluster compound made from a Keggin anion ([PMo 12 O 40 ] 3− ), an organic cation (o-xylylenebis(triphenylphosphonium)), and a complex (cobaltocenium). The new compound and its two...
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